Reference of 72287-26-4, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 72287-26-4, [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), introducing its new discovery.
Functional nanosized cage complexes with an octahedral framework have been synthesized by the facile self-assembly reactions of six 90 Pd II-containing compounds {[Pd(dppf)(OTf)2] or [Pd(PPh 3)(OTf)2], dppf = 1,1?-bis(diphenylphosphanyl) ferrocene, OTf = trifluoromethylsulfonate} and four 120 functional tritopic ligands [2,4,6-tri(4-pyridyl)-1,3,5-triazine] in acetone. Diffusion-ordered NMR spectroscopy (DOSY) and AFM images clarify the formation of 3-4 nm nanoparticles. These highly symmetrical cage complexes are discrete, face-directed, functional nanoparticles with symmetrical octahedral structures. The self-assembled functional cage complexes exhibit interesting electrochemical activities, and thus will potentially be useful in the catalysis of redox reactions, the encapsulation of sizeable guest molecules and the control of organic synthetic reactions. The appropriate stoichiometric combination of 90 PdII-containing units with 120 tritopic units affords octahedral symmetrical nanocages through covalently linked functional groups, which exhibit interesting electrochemical activities. Copyright
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Reference of 72287-26-4. In my other articles, you can also check out more blogs about 72287-26-4
Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method