14220-64-5, Name is Bis(benzonitrile)palladium chloride, belongs to catalyst-palladium compound, is a common compound. COA of Formula: C14H10Cl2N2PdIn an article, once mentioned the new application about 14220-64-5.
The crystal structure of the complex [Cu(bbimpy) (H2O)2(ONO2)](NO3)·H 2O (bbimpy=2,6-bis(2-benzimidazolyl)pyridine) has been determined by X-ray diffraction methods. It crystallises in the monoclinic space group P21/n, with Z=4 in a cell of dimensions a=13.350(1), b=7.820(1), c=21.484(1) A, beta=92.26(1). The structure is built up of [Cu(bbimpy) (H2O)2(ONO2)]+ cations, NO-3 anions and crystal lattice water molecules, with a 4 + 1 + 1 pseudo-octahedral geometry for the CuN3OO?O? chromophores. In the EPR spectrum exchange coupling between Cu(II) chromophores of different orientation is observed, and molecular g values, compatible with the crystallographic data, could be calculated.
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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method