9-Sep-2021 News New explortion of 32005-36-0

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32005-36-0, Name is Bis(dibenzylideneacetone)palladium, belongs to catalyst-palladium compound, is a common compound. Computed Properties of C34H28O2PdIn an article, once mentioned the new application about 32005-36-0.

Treatment of the unsymmetrical beta-iminoamine ligands [PhCN(Ar)CHCNH(Ar)Me] with the zerovalent complex Pd(dba)2 in the presence of the methallyloxyphosphonium salt, gives high yields of the cationic beta-diimine complexes [PhCN(Ar)CH2CN(Ar)(Me)Pd(eta3-C4H7)]+[PF6]- (Ar = 2-Me-C6H4 (7); 2-MeO-C6H4 (8); 2,6-Me2-C6H3 (9); 2,6-iPr2-C6H3 (10)). All the new complexes have been characterised by NMR and IR spectroscopy. The structure of the cationic methallyl palladium complex (10) has been solved by X-ray crystallography.

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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method