Top Picks: new discover of Pd2(DBA)3

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52409-22-0, Name is Pd2(DBA)3, belongs to catalyst-palladium compound, is a common compound. Quality Control of Pd2(DBA)3In an article, once mentioned the new application about 52409-22-0.

Vinylidenation of Organoboronic Esters Enabled by a Pd-Catalyzed Metallate Shift

Organoboron ?ate? complexes undergo a net vinyl insertion reaction to give 1,1-disubstituted alkenyl boronic esters when treated with stoichiometric allyl acetate and a palladium catalyst. Reactions that employ vinyllithium afforded good to excellent yields after one hour, while reactions that employ vinylmagnesium chloride furnished modest to good yields after 18 hours.

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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method