Extracurricular laboratory:new discovery of Bis(tri-tert-butylphosphine)palladium

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53199-31-8, Name is Bis(tri-tert-butylphosphine)palladium, belongs to catalyst-palladium compound, is a common compound. Computed Properties of C24H54P2PdIn an article, once mentioned the new application about 53199-31-8.

The impact of palladium(II) Reduction pathways on the structure and activity of palladium(0) catalysts

Two roads diverged: The mechanism of insitu PdII catalyst activation to generate an active {LnPd0} catalyst from an air-stable PdII precursor was examined using the standard conditions of a Miyaura borylation reaction. Two pathways for catalyst activation exist under these conditions, producing two structurally and chemically distinct {LnPd0} complexes (see scheme). Copyright

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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method