Chemistry is traditionally divided into organic and inorganic chemistry. name: Bis(tri-tert-butylphosphine)palladium, The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent£¬Which mentioned a new discovery about 53199-31-8
Formation of four different aromatic scaffolds from nitriles through tandem divergent catalysis
A zinc bromide complex, formed by the sequential reaction of nitriles with a Reformatsky reagent and terminal alkynes, is used as an intermediate for divergent palladium-catalyzed reactions. The reaction pathway of the intermediate is precisely controlled by the choice of the reaction solvent or the palladium catalyst to quickly form four different aromatic scaffolds – arylamines, aminoindenes, pyrroles, and quinolines – starting from readily available nitriles.
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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method