Synthetic Route of 52522-40-4, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 52522-40-4, Tris(dibenzylideneacetone)dipalladium-chloroform, introducing its new discovery.
Palladium-catalyzed regio- and diastereoselective tandem silastannylation/allyl addition of allene aldehydes and allene ketones: Synthesis of cis cyclopentanols and cyclohexanols
Two in one: the palladium-catalyzed regio- and diastereoselective silastannylation of allene aldehydes and ketones and the subsequent allyl addition to the carbonyl group gives rise to cis-cycloalkanols (see scheme; n = 1, 2; R = H, CH3; X = NTs, O, C(CO2Et)2, etc.). This tandem process requires a single catalyst and is carried out at a constant temperature.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Synthetic Route of 52522-40-4. In my other articles, you can also check out more blogs about 52522-40-4
Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method