In heterogeneous catalysis, the catalyst is in a different phase from the reactants. Safety of Pd2(DBA)3, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 52409-22-0, name is Pd2(DBA)3. In an article£¬Which mentioned a new discovery about 52409-22-0
PdII complexes of [44]-and [46]decaphyrins: The largest hueckel aromatic and antiaromatic, and Moebius aromatic macrocycles
Reductive metalation of [44]decaphyrin with [Pd2-(dba)3] provided a Hueckel aromatic [46]decaphyrin PdII complex, which was readily oxidized upon treatment with DDQ to produce a Hueckel antiaromatic [44]decaphyrin PdII complex. In CH2Cl2 solution the latter complex underwent slow tautomerization to a Moebius aromatic [44]decaphyrin PdII complex which exists as a mixture of conformers in dynamic equilibrium. To the best of our knowledge, these three PdII complexes represent the largest Hueckel aromatic, Hueckel antiaromatic, and Moebius aromatic complexes to date.
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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method