Extracurricular laboratory:new discovery of 1,1′-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

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Chemistry is traditionally divided into organic and inorganic chemistry. Application In Synthesis of 1,1′-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex, The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent£¬Which mentioned a new discovery about 95464-05-4

Developing an ionic medium for ligandless-palladium-catalysed Suzuki and Heck couplings

High-melting-point alkylammonium tetrafluoroborates melt with water or toluene to form biphasic mixtures at much lower temperatures than their normal melting points, thus could serve as green reaction media for Suzuki and Heck couplings. Advantages of using the aqueous-ammonium biphasic catalytic system include: (1) working well with a ligandless palladium catalyst, (2) solving the solubility problem of organic substrates and (3) simplifying work-up procedures for both separation of products and recycling of reaction media.

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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method