Discovery of

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Treatment of allenic bromoalkenes bearing a nucleophilic moiety with a catalytic amount of palladium(0) in the presence of TBAF or Cs 2CO3 in MeCN affords bicyclic heterocycles in good to high yields, through zipper-mode cascade cyclisation. The Royal Society of Chemistry.

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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method