One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, SDS of cas: 32005-36-0, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 32005-36-0, Name is Bis(dibenzylideneacetone)palladium, molecular formula is C34H28O2Pd
Synthesis of a new family of heterobimetallic tetranuclear sulfido clusters with Mo2Ni2Sx (x = 4 or 5) or Mo3M?S4 (M? = Ru, Ni, Pd) cores
Treatment of [Cp*Mo(SBut)3] (1; Cp* = eta5-C5Me5) with [Fc][PF6] (Fc = ferrocene) afforded the cationic sulfido-bridged dinuclear complex [(Cp*MoS)(mu2-S)2(Cp*Mo)(S2 But)][PF6] (2) and the cationic incomplete cubane-type complex[(Cp*Mo)3(mu2-S)3 (mu3-S)][PF6] (3) in a ratio of ca. 1:4. The dinuclear complex 2 reacted with [NiCl2(PPh3)2] and [Ni(cod)2] (cod = 1,5-cyclooctadiene) to give the heterobimetallic cluster [(Cp*Mo)2{Ni(PPh3)}2 (mu2-S)2 (mu3-S)3] [PF6] (4) with an unprecedented Mo2Ni2 S5 core and the edge-linked quadruple cubane-type cluster [(Cp*Mo)2Ni2(mu3-S)2 (mu4-S)2]4[PF6]4 (5) with four Mo2Ni2S4 cores, respectively. On the other hand, the incomplete cubane-type cluster 3 serves as a good precursor to the heterobimetallic cubane-type clusters [(Cp*Mo)3 (mu3-S)4M?L][PF6] (M? = Ru, Ni, and Pd).
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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method