72287-26-4, Name is [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), belongs to catalyst-palladium compound, is a common compound. Recommanded Product: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)In an article, once mentioned the new application about 72287-26-4.
Total synthesis of an atropdiastereomer of RP-66453 and determination of its absolute configuration
The absolute configuration (aR, S, S, S, S, S) was assigned to the natural product RP-66453 (1) after the total synthesis of its atropdiastereomer and spectroscopic studies on the two compounds. A sequence of SNAr-based cyclo-etherification and an intramolecular atropdiastereoselective Suzuki-Miyaura coupling were used for the construction of the elusive A-B-O-C bicyclic skeleton of RP-66453.
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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method