Electric Literature of 14220-64-5, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 14220-64-5, Bis(benzonitrile)palladium chloride, introducing its new discovery.
Binuclear and polynuclear transition metal complexes with macrocyclic ligands. 4. New polydentate azomethine ligands based on 2,5-diformylpyrrole and 2,6-diformylpyridine
The reactions of 2,5-diformylpyrrole (1) and 2,6-diformylpyridine (2) with propane-1,3-diamine afforded new macrocyclic Schiff’s bases 5 and 6, respectively. Their structures were established by NMR spectroscopy and mass spectrometry. Binuclear copper(II) and nickel(II) complexes with ligand 5 were synthesized. Pentadentate Schiff’s base, viz., 2,6-bis[(2-aminophenylimino) methyl]pyridine, was prepared by demetallation of its complex with Cd(ClO 4)2 using Na2S. In solutions, the latter Schiff’s base is quantitatively transformed into 2,6-bis(benzoimidazolyl) pyridine under the action of atmospheric oxygen or other mild oxidizing agents.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Electric Literature of 14220-64-5. In my other articles, you can also check out more blogs about 14220-64-5
Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method