One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, SDS of cas: 95464-05-4, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 95464-05-4, Name is 1,1′-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex, molecular formula is C35H32Cl4FeP2Pd
A series of palladium thiolate complexes of the type [Pd(dppf) (SRF)2] have been synthesized in good yields by metathetical reactions of [Pd(dppf)Cl2] with [Pb(SRF)2], (SRF=- SC6F5, -SC6F4 -4-H, -SC6H4-2-CF3, -SC6H4-4-F, – SC6H4-3-F) and their crystal structures determined. The effect of the different thiolates in the structural properties of the complexes both in the solid state and in solution have been analyzed. Heck coupling reactions were carried out using the complexes [Pd(dppf)(SRF)2], SRF =-SC6F5 (1), -SC6 F4-4-H (2), -SC6H4 -2-CF3 (3), -SC6H4-4-F (4), -SC6H4-3-F (5) as catalysts in order to examine both the effect of the thiolates and the P-Pd-P bite angles in the reaction of bromobenzene and styrene. The results obtained indicate that electron-withdrawing substituents may favor higher yields in the Pd catalyzed Heck reaction using [Pd(dppf)(SRF) 2] as catalysts.
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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method