Awesome Chemistry Experiments For Tetrakis(acetonitrile)palladium(II) tetrafluoroborate

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A Pd(II)-catalyzed direct selective fluorination reaction of carboranes using a F+ reagent has been developed, leading to a series of polyfluorocarboranes in high isolated yields. The mechanism involving electrophilic B-H activation, oxidation of Pd(II) by F+ species, and reductive elimination is proposed.

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Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method