Chemistry is traditionally divided into organic and inorganic chemistry. name: Bis(dibenzylideneacetone)palladium, The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent，Which mentioned a new discovery about 32005-36-0
1-Alkyl-2-methylenecyclopropanes react with silylboronic esters under mild conditions in the presence of a phosphine-free platinum catalyst, giving 3-substituted 2-boryl-4-silyl-1-butenes through selective cleavage of the less hindered proximal C-C bond of the cyclopropane ring. The steric bulk of the silyl group of the silylboronic esters was critical for efficient formation of the silaboration products, and i-PrPh2Si-B(pin) was developed as a silylboronic ester of choice.
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Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method