52522-40-4, Name is Tris(dibenzylideneacetone)dipalladium-chloroform, belongs to catalyst-palladium compound, is a common compound. Computed Properties of C52H43Cl3O3Pd2In an article, once mentioned the new application about 52522-40-4.
Participation of chiral sulfinyl functionality in palladium-catalyzed asymmetric reactions is demonstrated by using chiral sulfoxides as chiral ligands or chiral substrates. New chiral ligands, o-(phosphinoamino)phenyl and o-phosphinophenyl sulfoxides, have been developed. The structure of an intermediary palladium complex was determined by X-ray crystallographic analysis. The palladium-catalyzed asymmetric 1,3-rearrangements of (1,3-butadienyl)cyclopropanes bearing chiral sulfinyl groups to cyclopentenes are described. The participation of the chiral sulfinyl group to the palladium catalyst is described. (C) 2000 Elsevier Science Ltd All rights reserved.
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Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method