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Control over the integrative self-sorting of metallo-supramolecular assemblies opens up possibilities for introducing increased complexity and function into a single self-assembled architecture. Herein, the relationship between the geometry of three ligand components and morphology of three self-sorted heteroleptic [Pd2L2L?2]4+ cages is examined. Pd-mediated assembly of two bis-monodentate pyridyl ligands with native bite angles of 75 and 120 affords a cis-[Pd2L2L?2]4+ cage while the same reaction with two ligands with bite angles of 75 and 60 gives an unprecedented, self-penetrating structural motif; a trans-[Pd2(anti-L)2L?2]4+ heteroleptic cage with a ?doubly bridged figure eight? topology. Each heteroleptic assembly can be formed by cage-to-cage conversion of the homoleptic precursors and morphological control of [Pd2L2L?2] cages is achieved by selective ligand displacement transformations in a system of three ligands and at least six possible cage products.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Product Details of 21797-13-7, you can also check out more blogs about21797-13-7
Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method