Some scientific research about Bis(tri-tert-butylphosphine)palladium

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53199-31-8, Name is Bis(tri-tert-butylphosphine)palladium, belongs to catalyst-palladium compound, is a common compound. Recommanded Product: 53199-31-8In an article, once mentioned the new application about 53199-31-8.

A palladium-catalyzed insertion copolymerization of vinyl chloride (VC) and ethylene gave chlorinated polyethylene with CH3CHCl(CH 2)n units (see scheme; C blue, O red, Pd orange, S yellow). The CH3CHCl end groups form by 2,1-insertion of VC into palladium hydride complexes, as revealed by detailed labeling studies. This first example of VC incorporation (up to 0.4 mol %) clearly shows that insertion (co)polymerization of VC is in principle feasible.

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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method