Synthetic Route of 14871-92-2, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 14871-92-2, (2,2′-Bipyridine)dichloropalladium(II), introducing its new discovery.
1p;&-5q; 1 The reactions of [Tl2{S2C=C{C(O)Me}2}]n with [MCl2L2] (1:1) or with [MCl2(NCPh)2] and PPh3 (1:1:2) give complexes [M{eta2-S2C=C{C(O)Me}2}L2] [M = Pt, L2 = 1,5-cyclooctadiene (cod) (1); L2 = bpy, M = Pd (2a), Pt (2b), L = PPh3, M = Pd (3a), Pt (3b)] whereas with MCl2 and QCl (2:1:2) anionic derivatives Q2[M{eta2-S2C=C{C(O)Me}2}2] [M = Pd, Q = NMe4 (4a), Ph3P=N=PPh3 (PPN) (4a?), M = Pt, Q = NMe4 (4b)] are produced. Complexes 1 and 3 react with AgClO4 (1:1) to give tetranuclear complexes [{ML2}2Ag2-{mu2, eta2-(S,S?)-{S2C=C{C (O)Me}2}2}](ClO4)2 [L = PPh3, M = Pd (5a), Pt (5b), L2 = cod, M = Pt (5b?)], while the reactions of 3 with AgClO4 and PPh3 (1:1:2) give dinuclear [{M(PPh3)2}{Ag(PPh3)2} {mu2,eta2-(S,S?) -{S2C=C{C(O)Me}2}}]ClO4 [M = Pd (6a), Pt (6b)]. The crystal structures of 3a, 3b, 4a, and two crystal forms of 5b have been determined. The two crystal forms of 5b display two {Pt(PPh3)2}{mu2,eta2- (S,S?)-{S2C=C{C(O)Me}2}2} moieties bridging two Ag(I) centers.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Synthetic Route of 14871-92-2. In my other articles, you can also check out more blogs about 14871-92-2
Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method