Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments. SDS of cas: 52522-40-4. Introducing a new discovery about 52522-40-4, Name is Tris(dibenzylideneacetone)dipalladium-chloroform
The oxime-substituted NCN-pincer molecules HON{double bond, long}CH-1-C6H3(CH2NMe2)2-3,5 (2a) and HON{double bond, long}CH-4-C6H2(CH2NMe2)2-2,6-Br-1 (2b) were accessible by treatment of the benzaldehydes H(O)C-4-C6H3(CH2NMe2)2-3,5 (1a) and H(O)C-4-C6H2(CH2NMe2)2-2,6-Br-1 (1b) with an excess of hydroxylamine. In the solid state both compounds are forming polymers with intermolecular O-H?N connectivities between the Me2NCH2 substituents and the oxime entity of further molecules of 2a and 2b, respectively. Characteristic for 2a and 2b is a helically arrangement involving a crystallographic 21 screw axis of the HON{double bond, long}CH-1-C6H3(CH2NMe2)2-3,5 and HON{double bond, long}CH-4-C6H2(CH2NMe2)2-2,6-Br-1 building blocks. The reaction of 2b with equimolar amounts of [Pd2(dba)3 · CHCl3] (3) (dba = dibenzylidene acetone) or [Pt(tol)2(SEt2)]2 (4) (tol = 4-tolyl) gave by an oxidative addition of the C-Br unit to M coordination polymers with a [(HON{double bond, long}CH-4-C6H2(CH2NMe2)2-2,6)MBr] repeating unit (5: M = Pd, 6: M = Pt). Complexes 5 and 6 are in the solid state linear hydrogen-bridged polymers with O-H?Br contacts between the oxime entities and the metal-bonded bromide.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.SDS of cas: 52522-40-4, you can also check out more blogs about52522-40-4
Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method