One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, Product Details of 52522-40-4, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 52522-40-4, Name is Tris(dibenzylideneacetone)dipalladium-chloroform, molecular formula is C52H43Cl3O3Pd2
The RhI, RuII, PdI and NiII complexes of the aminobis(phosphonite), PhN(P(OC6H4OMe-o)2)2 (1) are reported. The reactions of 1 with [Rh(COD)Cl]2 in 1:1 and 2:1 molar ratio afford the mono- and diolefin substituted chloro bridged chelate complexes, [(COD)Rh2(mu2-Cl)2{PhN(P(OC6H4OMe-o)2)2}] (2) and [Rh(mu2-Cl){PhN(P(OC6H4OMe-o)2)2}]2 (3), respectively. Similarly, the cationic mono- and bis-chelate complexes, [Rh(COD){PhN(P(OC6H4OMe-o)2)2}]OTf (4) and [Rh{PhN(P(OC6H4OMe-o)2)2}2]OTf (5) are obtained by treating 1 with [Rh(COD)Cl]2 in the presence of AgOTf in appropriate ratios. The dinuclear RhI carbonyl complex, [RhCl(CO){mu-PhN(P(OC6H4OMe-o)2)2}]2 (6) is prepared by treating 1 with 0.5 equiv. of [Rh(CO)2Cl]2. Reaction of 1 with cis-[NiBr2(DME)] (DME = 1,2-dimethoxyethane) affords [{PhN(P(OC6H4OMe-o)2)2}NiBr2] (7) whereas with [Ru-(eta6-p-cymene)Cl2]2 in refluxing THF medium produces an interesting and rare bimetallic RuII complex, [(eta6-p-cymene)Ru(mu2-Cl)3Ru{PhN(P(OC6H4OMe-o)2)2}Cl] (8). Redox condensation of the Pd0 and PdII derivatives with 1 affords the dinuclear PdI complex, [PdBr{mu-PhN(P(OC6H4OMe-o)2)2}]2 (9). The formation and structure of complexes 2-9 are assigned through various spectroscopic and micro analysis data. The molecular structures of 5 and 7-9 are confirmed by single crystal X-ray diffraction studies.
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Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method