Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Reference of 21797-13-7. In my other articles, you can also check out more blogs about 21797-13-7
Reference of 21797-13-7, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 21797-13-7, Tetrakis(acetonitrile)palladium(II) tetrafluoroborate, introducing its new discovery.
The synthesis and X-ray crystal structure of aneN2S)>(BF4)2 (py2<9>aneN2S = 1-thia-4,7-bis(pyridylmethyl)diazacyclononane)(P21/n, a = 10.233(4) Angstroem, b = 11.484(5) Angstroem, c = 19.913(6) Angstroem, beta = 94.03(4) deg, V = 2334(2) Angstroem3, R = 0.0705, Rw = 0.0759) are presented.The crystal structure indicates a long range interaction (2.92 Angstroem) between the planar palladium and the apical sulphur atom.Although this distance is longer than the value for Pd-S bond observed normally there is evidence for a net positive interaction provided by the solution structure as determined by NMR spectroscopy.Comparative analysis of the structural features exhibited by this complex with similar nine-membered chelating ligands emphasizes the presence of an axial Pd-S bond.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Reference of 21797-13-7. In my other articles, you can also check out more blogs about 21797-13-7
Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method