Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 92390-26-6, is researched, SMILESS is [Cl-][Ru+2]1234567(C8(C)=C4(C)[C-]5(C)C6(C)=C87C)[CH]9=[CH]1CC[CH]2=[CH]3CC9, Molecular C18H28ClRuJournal, Zeitschrift fuer Anorganische und Allgemeine Chemie called Pentamethylcyclopentadienyl(η6-cyclooctatrienyl)ruthenium tetrachlorozincate, [RuCp*(η6-C8H10)]2ZnCl4, Author is Bruce, Michael I.; Joly, Damien; Skelton, Brian W.; White, Allan H., the main research direction is crystal structure ruthenium pentamethylcyclopentadienyl cyclooctatrienyl tetrachlorozincate preparation; mol structure ruthenium pentamethylcyclopentadienyl cyclooctatrienyl tetrachlorozincate.Reference of Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium.
The crystal and mol. structures of the title compound, the first for a complex of the type [RuCp*(η6-C8-ring)]+, is presented, the material being obtained serendipitously from a reaction between RuCl(cod)Cp* and 1-ferrocenylbuta-1,3-diyne in the presence of ZnCl2. Ru-C(Cp*) distance (2.21 Å) is appreciably longer than in RuCp*2 (2.18 Å) and similar to the value for the Ru-η6 component (2.22 Å).
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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method