Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 78-50-2, is researched, Molecular C24H51OP, about Origin of the Anomalous Temperature Dependence of the Photochromic Reaction of Cu-Doped ZnS Nanocrystals, the main research direction is Temperature Dependence Photochromic Reaction Cu Doped ZnS Nanocrystals Diphenylnaphthopyran.Safety of Tri-n-octylphosphine Oxide.
The temperature dependence of the color fading process of thermally reversible photochromic reactions is one of the most important challenges for their industrial applications. Generally, photochromic reactions of organic mols. have a strong temperature dependence due to the occurrence of large conformational changes during the reactions. In contrast, we recently reported that the photochromic reaction of Cu-doped ZnS nanocrystals (NCs) exhibits a very small temperature dependence around room temperature However, the mechanism underlying this phenomenon has not been clarified yet. Here, we reveal that the anomalous temperature dependence of Cu-doped ZnS NCs originates from the balance between the temperature dependence of the charge recombination and that of the adsorption/desorption of water mols. on the surface of the NCs, which act as hole acceptors. Exploring temperature-insensitive photochromic reactions is important not only for gaining fundamental insight into nanomaterials but also for developing novel photochromic materials for outdoor applications.
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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method