Cambeiro, Fermin; Lopez, Susana; Varela, Jesus A.; Saa, Carlos published the article 《Cyclization by Catalytic Ruthenium Carbene Insertion into Csp3-H Bonds》. Keywords: alkynyl acetal ether amine ruthenium carbene insertion cyclization; carbon hydrogen activation mechanism hydride shift cyclization.They researched the compound: Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium( cas:92390-26-6 ).Related Products of 92390-26-6. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:92390-26-6) here.
A novel tandem Ru-catalyzed carbene addition to terminal alkynes/insertion into Csp3-H bonds in alkynyl acetals, ethers, and amines has been accomplished under mild reaction conditions. This cascade provides an efficient approach to form complex spiro and fused bicyclic structures by 1,5- and 1,6-hydride shift/cyclization sequences from vinylcarbene Ru intermediates.
This literature about this compound(92390-26-6)Related Products of 92390-26-6has given us a lot of inspiration, and I hope that the research on this compound(Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method