Analyzing the synthesis route of 92390-26-6

In some applications, this compound(92390-26-6)Reference of Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.

In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Ruthenium catalyzed synthesis of unsaturated acetals and aldehydes via C-C bond coupling of alkynes with allyl alcohol, published in 1994-11-21, which mentions a compound: 92390-26-6, mainly applied to ruthenium catalyst coupling alkyne allyl alc; unsaturated aldehyde acetal; phenylacetylene coupling allyl alc catalyst, Reference of Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium.

Terminal alkynes and allyl alc. are coupled, with carbon-carbon bond formation, in the presence of a RuIV(C5Me5) catalyst, to give γ,δ-unsaturated acetals and with [{RuCl(C5Me5)}4] or [RuCl(cod)(C5Me5)] preferentially to produce the branched γ,δ-unsaturated aldehyde. Thus, phenylacetylene and allyl alc. afforded unsaturated acetals CH2:CPhCH2CH2CH(OCH2CH:CH2)2 and PhCH:CHCH2CH2CH(OCH2CH:CH2)2 or the corresponding unsaturated aldehydes.

In some applications, this compound(92390-26-6)Reference of Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.

Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method