Application of 21797-13-7, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 21797-13-7, Tetrakis(acetonitrile)palladium(II) tetrafluoroborate, introducing its new discovery.
The intrinsic features of (hetero-arene)-metal interactions have been elusive mainly because the systematic structure analysis of non-anchored hetero-arene-metal complexes has been hampered by their labile nature. We report successful isolation and systematic structure analysis of a series of non-anchored indole-palladium(II) complexes. It was revealed that there is a sigma-pi continuum for the indole-metal interaction, while it has been thought that the dominant coordination mode of indole to a metal center is the Wheland-intermediate-type sigma-mode in light of the seemingly strong electron-donating ability of indole. Several factors which affect the sigma- or pi-character of indole-metal interactions are discussed. Continuum split: The isolation and systematic structural analysis of non-anchored indole-palladium(II) complexes revealed that there is a sigma-pi continuum for heteroarene-metal complexes. These findings may provide insights into key catalytic intermediates of metal-catalyzed heteroarene transformations.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Application of 21797-13-7. In my other articles, you can also check out more blogs about 21797-13-7
Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method