32005-36-0, Name is Bis(dibenzylideneacetone)palladium, belongs to catalyst-palladium compound, is a common compound. Recommanded Product: 32005-36-0In an article, once mentioned the new application about 32005-36-0.
For PPh3, mixtures of Pd(dba)2 and nTFP (TFP = tri-2-furylphosphine, n ? 2) in DMF and THF (S) lead to the formation of Pd(dba)(TFP)2, SPd(TFP)3 in equilibrium with SPd-(TFP)2. The substitution of dba by the phosphine in Pd(dba)L2 to form SPdL3 is easier for L = TPF than for L = PPh3. The less ligated complex SPd(TFP)2 is the reactive species in the oxidative addition with phenyl iodide. In THF, {Pd(dba)2 + nTFP}, a mixture often used as a catalyst promoter in several synthetic organic reactions, is found to be less reactive than {Pd(dba)2 + nPPh3} for small values of n (n = 2 or 4) whereas it is more reactive for higher values of n (n > 6). Conversely, in DMF, {Pd(dba)2 + nTFP} is always found to be more reactive than {Pd(dba)2 + nPPh3} whatever n (n ? 2).
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Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method