A new application about Pd2(DBA)3

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52409-22-0, Name is Pd2(DBA)3, belongs to catalyst-palladium compound, is a common compound. Computed Properties of C51H42O3Pd2In an article, once mentioned the new application about 52409-22-0.

Palladium-mediated 11C-carbonylations using aryl halides and cyanamide

A robust and high-yielding radiochemical synthesis of 11C-N-cyanobenzamides using a palladium-mediated aminocarbonylation with 11C-CO, aryl halides and cyanamide is described. The bidentate ligand 1,1?-bis(diphenylphosphino)ferrocene provided 11C-N-cyanobenzamides from aryl-iodides, bromides, triflates and even chlorides in 28-79% radiochemical yield after semi-preparative HPLC. To further highlight the utility of this method, novel 11C-N-cyanobenzamide analogs of flufenamic acid, meflanamic acid, dazoxiben and tamibarotene were synthesized in 34-71% radiochemical yields.

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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method