Quality Control of Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium, is researched, Molecular C18H28ClRu, CAS is 92390-26-6, about Hexamethyl 13,14-dioxapentacyclo[8.2.1.14,7.02,9.03,8]tetradeca-5,11-diene-1,4,5,6,11,12-hexacarboxylate.
In the title compound, C24H24O14, the stereochem. at the cyclobutane ring is cis-anti-cis and the -COOMe groups in the bicyclic rings are syn to each other. The mol. lies on a 2-fold rotation axis. In the crystal, weak C-H···O H bonds connect mols. into chains along [001], forming R22(10) rings. Crystallog. data and at. coordinates are given.
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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method