As a common heterocyclic compound, it belong catalyst-palladium compound,Tris(dibenzylideneacetone)dipalladium-chloroform,52522-40-4,Molecular formula: C52H43Cl3O3Pd2,mainly used in chemical industry, its synthesis route is as follows.,52522-40-4
General procedure: 0.1127g (0.4871mmol) of Me-TtBQ, 0.1755g (1.218mmol) of dmfu and 0.2101g (0.2030mmol) of [Pd2(DBA)3¡¤CHCl3] were dissolved under inert atmosphere (Ar) in 30ml of anhydrous acetone. The mixture was stirred for 60min and eventually treated with active charcoal for 5/10min and filtered on Celite filter. The resulting yellow solution was dried under vacuum and the residual treated with diethyl ether, filtered off, washed with diethyl ether in excess and dried under vacuum. 0.1452g (yield 75%) of the title compound was obtained as pale yellow microcrystals.
With the synthetic route has been constantly updated, we look forward to future research findings about Tris(dibenzylideneacetone)dipalladium-chloroform,belong catalyst-palladium compound
Reference£º
Article; Canovese, Luciano; Visentin, Fabiano; Biz, Chiara; Scattolin, Thomas; Santo, Claudio; Bertolasi, Valerio; Polyhedron; vol. 102; (2015); p. 94 – 102;,
Chapter 1 An introduction to palladium catalysis
Palladium/carbon catalyst regeneration and mechanical application method