Archives for Chemistry Experiments of 21797-13-7

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Light-triggered guest uptake and release by a photochromic coordination cage

A guiding light is sufficient to switch back and forth between the flexible and the stretched, rigid form of a self-assembled coordination cage based on two square-planar-coordinated PdII ions and four ligands with a photochromic dithienylethene (DTE) backbone. The light-driven interconversion is clean and reversible and allows to control the encapsulation and release of the guest [B12F12]2-. Copyright

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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method