Archives for Chemistry Experiments of 32005-36-0

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One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, name: Bis(dibenzylideneacetone)palladium, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 32005-36-0, Name is Bis(dibenzylideneacetone)palladium, molecular formula is C34H28O2Pd

Crystal Structure of Cationic eta3-Methallylpalladium Complexes Bearing Aliphatic Iminopyridine Ligands

Three aliphatic ligands are synthesized and fully characterized by IR, 1H and 13C NMR spectroscopy. These ligands react with a zerovalent compound Pd(dba)2 in the presence of methallyloxytris(dimethylamino) phosphonium hexafluorophosphate salt [C4H7OP(NMe2)3]+PF6? as an allylating agent for the synthesis of cationic eta3-methallylpalladium complexes to give three cationic mononuclear eta33-methallylpalladium complexes in high yields. These formed complexes are characterized by IR, 1H NMR and 13C NMR spectroscopy. One of them is characterized by X-ray diffraction. A DFT-optimized structure is also discussed.

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Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method