Archives for Chemistry Experiments of Bis(benzonitrile)palladium chloride

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Synthetic Route of 14220-64-5, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.14220-64-5, Name is Bis(benzonitrile)palladium chloride, molecular formula is C14H10Cl2N2Pd. In a Article,once mentioned of 14220-64-5

Six complexes consisting of either 2,6-bis(1H-benzimidazol-2-yl)pyridine (bbp) or 2,2?:6?,2?-terpyridine (tpy) moieties coordinated to ruthenium(II) and attached to (pentaphenoxy)cyclotriphosphazene were synthesised and structurally characterised by single-crystal X-ray diffraction techniques. Two of the complexes are the first examples of structurally characterised mono-protonated Ru(bbp)(tpy) complexes. The new complexes were studied by NMR, electronic absorption and vibration spectroscopy to gain an understanding of their physical characteristics. Remarkably the mono-deprotonated form of the bbp ligand, but only when attached to (pentaphenoxy)cyclotriphosphazene by a pyridyl phosphoester linker, shows an equivalence of the benzimidazole/benzimidazolate moieties on the NMR time scale, but not on the electronic time scale, as evidenced by UV-Vis and resonance Raman spectroscopy.

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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method