One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, Recommanded Product: 21797-13-7, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 21797-13-7, Name is Tetrakis(acetonitrile)palladium(II) tetrafluoroborate, molecular formula is C8H12B2F8N4Pd
Palladium complexes containing large fused aromatic N-N ligands as efficient catalysts for the CO/styrene copolymerization
Bis(homoleptic) palladium(II) complexes of the extended aromatic ligands eilatin ([Pd(eil)2][BF4]2 (1a)) and dipyridophenazine ([Pd(dppz)2][BF4]2 (2a), [Pd(dppz)2][PF6]2 (2b)) were synthesized and employed in the copolymerization of carbon monoxide and styrene. The eilatin ligand in the complex [Pd(eil)2]-[BF4]2 is bound via its less hindered “head” coordination site. The X-ray structure of 2b was solved and indicated a highly twisted square planar geometry around the palladium center and the presence of pi-stacking interactions of two types. All complexes were found to be active catalysts for the synthesis of the syndiotactic CO/styrene polyketone, their activity exceeding that of the parent complex [Pd(phen)2]-[BF4]2.
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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method