Chemistry is traditionally divided into organic and inorganic chemistry. Computed Properties of C8H12B2F8N4Pd, The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent£¬Which mentioned a new discovery about 21797-13-7
Chiral Self-Sorting of trans-Chelating Chiral Ligands upon Formation of PdII Complexes
Two bis(3-pyridyl) ligands 1 and 2 based on a planar chiral [2.2]paracyclophane scaffold were synthesized in enantiomerically pure forms. These ligands act as trans-chelating ligands for square-planar-coordinated metal centres such as palladium(II) ions. Upon forming mononuclear homochiral [ML2] complexes, they show complete chiral self-sorting in a narcissistic self-recognition manner as proven by NMR spectroscopy, mass spectrometry and single-crystal X-ray diffraction.
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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method