32005-36-0, Name is Bis(dibenzylideneacetone)palladium, belongs to catalyst-palladium compound, is a common compound. Formula: C34H28O2PdIn an article, once mentioned the new application about 32005-36-0.
Palladium(II) complexes with phosphorus-nitrogen mixed donors. Efficient catalysts for the Heck reaction
Pd(II) complexes of phosphine-nitrogen (P-N) bidentate donors act as efficient catalysts for the Heck reaction. In a typical example, reaction of phenyl iodide with methyl acrylate in N-methylpyrrolidinone (NMP) at ca. 130C provides the Heck product with a turnover number of up to 106. In addition, the coupling reaction of 4-bromoacetophenone with olefin in a quantitative yield was achieved by using the same catalyst in the presence of sodium iodide.
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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method