Awesome Chemistry Experiments For 32005-36-0

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Reference of 32005-36-0, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.32005-36-0, Name is Bis(dibenzylideneacetone)palladium, molecular formula is C34H28O2Pd. In a Article,once mentioned of 32005-36-0

A highly chemoselective intermolecular [2+2+2] cycloaddition of 2eq. of terminal alkynes with dimethyl acetylenedicarboxylate, which enables the straightforward synthesis of dialkylated o-phthalates, was successfully accomplished using a ruthenium catalyst, Cp*RuCl(cod) (Cp*: pentamethylcyclopentadienyl, cod: 1,5-cyclooctadiene). The co- cyclotrimerisation of alkynes and acetylenedicarboxylates usually affords 1:2 adducts (1,2,3,4-benzenetetracarboxylates), however, in the present reaction 2: 1 adducts (o-phthalates) are the major products unprecedentedly.

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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method