Awesome Chemistry Experiments For 92390-26-6

From this literature《Ruthenium catalyzed regioselective hydrophosphination of propargyl alcohols》,we know some information about this compound(92390-26-6)Formula: C18H28ClRu, but this is not all information, there are many literatures related to this compound(92390-26-6).

So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Jerome, Francois; Monnier, Florian; Lawicka, Hania; Derien, Sylvie; Dixneuf, Pierre H. researched the compound: Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium( cas:92390-26-6 ).Formula: C18H28ClRu.They published the article 《Ruthenium catalyzed regioselective hydrophosphination of propargyl alcohols》 about this compound( cas:92390-26-6 ) in Chemical Communications (Cambridge, United Kingdom). Keywords: alkenylphosphine preparation; propargyl alc regioselective stereoselective ruthenium catalyzed hydrophosphination phenylphosphine. We’ll tell you more about this compound (cas:92390-26-6).

Catalytic hydrophosphination of propargyl alcs. by ruthenium complexes RuCl(cod)(C5Me5) and RuCl(PPh3)2(C5Me5) led to formation of functionalized vinylphosphines, with linkage of the phosphorus atom to the terminal alkyne carbon, via a ruthenium vinylidene intermediate. For example, HCC(OH)(CH3)2 reacted with Ph2PH in the presence of catalytic RuCl(cod)(C5Me5) giving Ph2PCH:CHC(OH)(CH3)2 (81% yield, Z/E = 75/25).

From this literature《Ruthenium catalyzed regioselective hydrophosphination of propargyl alcohols》,we know some information about this compound(92390-26-6)Formula: C18H28ClRu, but this is not all information, there are many literatures related to this compound(92390-26-6).

Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method