Brief introduction of Bis(dibenzylideneacetone)palladium

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An alternative route to allylgermanes by the palladium-catalyzed reaction of germylsilanes with allylic halides

Pd(dba)2 (bis(dibenzylideneacetone)palladium complex) effectively catalyzes the reaction of (dimethylphenylgermyl)trimethylsilane with 2-alkenyl halides to bring about metal-, regio- and stereoselective metathesis resulting in the formation of 2-alkenylphenylgermanes with good yields. On the other hand, the reaction of (chlorodimethylgermyl)trimethylsilane with 2-alkenyl halides is effected by a palladium-phosphine complex to give 2-alkenylchlorogermanes selectively. Germylation of 3,4-dichloro-1-butene with (dimethylphenylgermyl)trimethylsilane forms 1,4-bis(dimethylphenylgermyl)-2-butene with a high yield.

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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method