Brief introduction of Tris(dibenzylideneacetone)dipalladium-chloroform

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Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments. category: catalyst-palladium. Introducing a new discovery about 52522-40-4, Name is Tris(dibenzylideneacetone)dipalladium-chloroform

Unexpected stability is observed for the palladacycloheptane rac-2, which is obtained as major product and single diastereomer from the cyclization of 1 and Pd. Up to a temperature of 50C 2 shows neither reductive elimination nor intramolecular insertion of another olefin.

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Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method