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32005-36-0, Name is Bis(dibenzylideneacetone)palladium, belongs to catalyst-palladium compound, is a common compound. Formula: C34H28O2PdIn an article, once mentioned the new application about 32005-36-0.
The stable complexes 2Cl(CO)L2> (L= PPh3, AsPh3, or PMePh2) and 2(PPh3)> have been prepared by oxidative addition of the radical (CF3)2NO. to trans- and either respectively.The compounds trans- (X = Br or l) react with the radical to give a mixture of 2>(PPh3)2> and .The platinum(II)complexes 2L2> (L= PPh3, AsPh3, or PMePh2) and the gold(I) complex (PPh3)>have been synthesized by metathetical exhange of the chlorine atoms in cis- and using2>.The weak nucleophile Na has been shown to react with the complexes ClO4 (M = RH or lr) to give the compounds trans-(CO)(PPh3)2>, while reaction with the complexes trans-BF4 (X = Cl, L = PPh3 or AsPh3; X = Br, L = PPh3) occurs at the carbonyl ligand giving L2>.The new iridium(I) complex trans-(CO)(PPh3)2> forms an oxygen comple in solution, and reacts with halogens, CF3CO2H, HgCl2 and C6H5CH2COCl to give the products (X= Cl or I), , respecyively, with loss of the (CF3)2NO ligand; unstable oxidative-addition products (R)I(CO)(PPh3)2> (R = CF3, CH3, or C2H5) have been characterized from the reactions with iodoalkanes.
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Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method