Product Details of 92390-26-6. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium, is researched, Molecular C18H28ClRu, CAS is 92390-26-6, about Tandem Catalytic Carbene Addition/Bicyclization of Enynes. One-Step Synthesis of Fluorinated Bicyclic Amino Esters by Ruthenium Catalysis. Author is Eckert, Matthieu; Monnier, Florian; Shchetnikov, Grigorii T.; Titanyuk, Igor D.; Osipov, Serguej N.; Toupet, Loiec; Derien, Sylvie; Dixneuf, Pierre H..
The reaction of diazo compounds with enynes, containing a fluorinated amino acid moiety, in the presence of the precatalyst Cp*(Cl)Ru(COD) leads to fluorinated alkenyl bicyclo[3.1.0]hexane and [4.1.0]heptane amino acid derivatives It is remarkable that the catalyst, in situ generated from ruthenium complex and diazo compound, completely inhibits the ring closing metathesis of enyne to the profit of tandem alkenylation/cyclopropanation with high stereoselectivity. The study shows that the Cp*(Cl)Ru moiety in ruthenacyclobutane favors reductive elimination vs. expected alkene metathesis.
This compound(Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium)Product Details of 92390-26-6 was discussed at the molecular level, the effects of temperature and reaction time on the properties of the compound were discussed, and the optimum reaction conditions were selected.
Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method