Synthetic Route of 205319-10-4, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 205319-10-4, Dichloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene]palladium(II), introducing its new discovery.
New palladium complexes of the type [PdCl2(eta2- P?P)] (1a,1b) and [PdCl2(eta2-P?S)] (1c,1d) have been synthesised by the reaction of PdCl2 with P,P and P,S type bidentate ligands in 1:1 mol ratio, where, P?P = 9,9-dimethyl-4,5- bis(diphenylphosphanyl) xanthene {Xantphos}(a) or bis(2- diphenylphosphanylphenyl)ether{DPEphos}(b); P?S = 9,9-dimethyl-4,5- bis(diphenyl -phosphanyl) xanthenemonosulfide {Xantphos(S)}(c) or bis(2-diphenylphosphanyl phenyl) ether monosulfide {DPEphos(S)}(d). The complexes are characterized by elemental analyses, mass spectrometry, 1H, 13C and 31P NMR spectroscopy together with the single crystal X-ray structure determination of 1a and 1d. The palladium atom in all the complexes occupies the centre of a slightly distorted square planar environment formed by a P atom, a P/S atom and two Cl atoms. The catalytic activities of 1a-1d investigated for Suzuki-Miyaura cross-coupling reactions at room temperature exhibit higher yield of the coupling products than catalysed by PdCl2 itself. Among 1a-1d, the palladium complexes of bidentate phosphine (1a, 1b) show higher efficacy than their monosulfide analogues (1c, 1d). However, the recycling experiments with the catalysts for a selected coupling reaction between 4-bromobenzonitrile and phenylboronic acid exhibit that 1c and 1d are more efficient than 1a and 1b, which may be due to the donor effect of the P,S ligands during catalytic reaction.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Synthetic Route of 205319-10-4. In my other articles, you can also check out more blogs about 205319-10-4
Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method