32005-36-0, Name is Bis(dibenzylideneacetone)palladium, belongs to catalyst-palladium compound, is a common compound. Formula: C34H28O2PdIn an article, once mentioned the new application about 32005-36-0.
Trans-4,5-bis(2-pyridyl)norbornane: A bidentate nitrogen ligand with a potentially large bite angle1
The coordination chemistry of the new chiral bidentate nitrogen ligand trans-4,5-bis(2-pyridyl)norbornane (Renorpy) towards palladium has been studied. The novel complexes (Renorpy)Pd(eta2-alkene) (eta2-alkene=maleic anhydride, tetracyanoethylene), (Renorpy)Pd(Me)Cl and (Renorpy)Pd(C(O)Me)Cl have been synthesized. Molecular modeling calculations gave a ‘natural’ bite angle for the Renorpy ligand of 115.5. Single crystal X-ray analyses of the complex (Renorpy)Pd(Me)Cl showed that the bite angle of the ligand in this complex is significantly smaller (93.7(2)) than the ‘natural’ one, which is caused by the electronic preference of palladium. To accommodate this smaller bite angle the palladium atom moves out of the pyridyl planes.
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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method