32005-36-0, Name is Bis(dibenzylideneacetone)palladium, belongs to catalyst-palladium compound, is a common compound. Safety of Bis(dibenzylideneacetone)palladiumIn an article, once mentioned the new application about 32005-36-0.
The diiridium tris(hydrosulfido) complex [Cp*Ir(mu2-SH)3IrCp*]Cl (2; Cp* = eta5-C5Me5) reacted with [NEt4 [SH] at room temperature for 3 h to afford the tetrakis(hydrosulfido) complex [Cp*Ir(SH)(mu2-SH)2IrCp*(SH)] (3). Complex 3 dissolved in benzene is thermally unstable and was converted into the triiridium sulfido-hydrosulfido cluster [(Cp*Ir)3(mu3-S)(mu2-S)(mu2 -SH)2] (4) at 50 C. The related triiridium cluster [(Cp*Ir)3(mu3-S)(mu2-SH)3] Cl (6) was obtained from either the reaction of 3 with 0.5 equiv of [(Cp*IrCl)2(mu2-H)2] or treatment of 2 with an equimolar amount of NEt3. Furthermore, reaction of 3 with 2 equiv of [Pd(PPh3)4 or a [Pd(dba)2]-PPha (dba = dibenzalacetone) mixture gave the Ir2Pd2 mixed-metal sulfido-hydrosulfido cluster [(Cp*Ir)2(SH)(mu3-S)2{Pd(PPh3 )}2(mu2-SH)] (8). X-ray analyses were undertaken to determine the detailed structures of 3, 4, 6, and 8.
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Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method