One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, Application In Synthesis of Pd2(DBA)3, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 52409-22-0, Name is Pd2(DBA)3, molecular formula is C51H42O3Pd2
Enantioselective Pd-catalyzed decarboxylative allylic alkylation of thiopyranones. Access to acyclic, stereogenic alpha-quaternary ketones
A catalytic, enantioselective decarboxylative allylic alkylation of 4-thiopyranones is reported. The alpha- quaternary 4-thiopyranones produced are challenging to access by standard enolate alkylation owing to facile ring-opening beta- sulfur elimination. In addition, reduction of the carbon-sulfur bonds provides access to elusive acyclic alpha-quaternary ketones. The alkylated products are obtained in up to 92% yield and 94% enantiomeric excess.
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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method