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Stable Palladium(0) and Palladium(II) Complexes Containing a New, Multifunctional and Semi-labile Phosphorus-Bisnitrogen Ligand
The new, multifunctional, semi-labile phosphorus-bisnitrogen ligand N-(2-diphenylphosphinobenzylidene)-2-(2-pyridyl)ethylamine, PNN, stabilises methyl(chloro)-, eta1-allyl(chloro)-, dichloro- and bis(tetrafluoroborate)palladium(II) PNN complexes in a terdentate coordination fashion, resulting in ionic palladium complexes, as well as an unprecedented palladium(0) PNN complex as is evidenced from 1H, 13C, 31P and 15N NMR spectra and an X-ray structural analysis of <(PNN)PdMe>+
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Recommanded Product: Tetrakis(acetonitrile)palladium(II) tetrafluoroborate, you can also check out more blogs about21797-13-7
Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method