Reference of 14220-64-5, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 14220-64-5, Name is Bis(benzonitrile)palladium chloride, molecular formula is C14H10Cl2N2Pd. In a Article，once mentioned of 14220-64-5
Mono-cationic Ru(II)-complexes [Ru(L)X(CH3CN)2]?X 1?4 (1, L = 2,6-bis(benzimidazol-2-yl) pyridine (L1), X = Cl; 2, L = L1, X = OTf; 3, L = 2-(N-benzyl-benzimidazole-2-yl)-6-(benzimidazole-2-yl)pyridine (L2), X = Cl; 4, L = 2,6-bis(N-benzyl-benzimidazole-2-yl)pyridine (L3), X = Cl) were prepared and fully characterized. The two acetonitrile ligands of each complex are coordinated to the metal center cis to each other. Complex 2 was also structurally characterized by X-ray crystallography. It was found that complexes 1?4 can catalyze the acceptorless dehydrogenation of primary alcohols to corresponding carboxylic acids and H2in the basic aqueous solution, and the reactivity follows the order 1 = 2 > 4 > 3. Furthermore, complexes 1 or 2 can efficiently catalyze the conversion of various primary alcohols to carboxylic acid in good yields (72%?98%) and high selectivity in an alcohol/CsOH system (1/1, mol/mol). Using an excess amount of alcohol to CsOH results in the formation of the carboxylic acid in higher yield (up to 100%, based on CsOH) and higher turnover numbers (TON ? 10000) accompanied by the H2evolution. Complexes 1 and 2 can act as a new class of phosphine- and N-heterocycle carbene free Ru(II) complexes for efficient conversion of primary alcohols to carboxylic acids and H2in a homogeneous system.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Reference of 14220-64-5. In my other articles, you can also check out more blogs about 14220-64-5
Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method